Igneous Rocks are formed by crystallization from a liquid, or magma.
They include two types:
Volcanic or extrusive igneous rocks wherein the magma cools and
crystallizes on the surface of the Earth
Intrusive or plutonic igneous rocks wherein the magma crystallizes at
depth in the Earth.
Magma is a mixture of liquid rock, crystals, and gas. Characterized
by a wide range of chemical compositions, with high temperature,
and properties of a liquid.
Magmas are less dense than surrounding rocks, and will therefore move
upward. If magma makes it to the surface it will erupt and later
crystallize to form an extrusive or volcanic rock. If it crystallizes
before it reaches the surface it will form an igneous rock at depth called
a plutonic or intrusive igneous rock. Because cooling of the magma takes
place at a different rate, the crystals that form and their
interrelationship (texture) exhibit different properties.
Fast cooling on the surface results in many small crystals or quenching to
a glass. Gives rise to aphanitic texture (crystals cannot be distinguished
with the naked eye), or obsidian (volcanic glass).
Slow cooling at depth in the earth results in fewer much larger
crystals , gives rise to phaneritic texture.
Porhpyritic texture develops when slow cooling is followed by rapid
cooling.
Phenocrysts = larger crystals, matrix or groundmass = smaller crystals.
Chemical composition of magma is controlled by the abundance of
elements in the earth. Si, Al, Fe, Ca, Mg, K, Na, H, and O make up 99.9%.
Since oxygen is so abundant, chemical analyses are usually given in terms
of oxides. SiO2 is the most abundant oxide.
Basaltic or gabbroic -- SiO2 45-55 wt%, high in Fe, Mg, Ca,
low in K, Na
Andesitic or Dioritic -- SiO2 55-65 wt%, intermediate. in Fe,
Mg, Ca, Na, K
Rhyolitic or Granitic -- SiO2 65-75%, low in Fe, Mg, Ca, high
in K, Na.
Gases - At depth in the Earth nearly all magmas contain gas. Gas
gives magmas their explosive character, because the gas expands as
pressure is reduced.
Higher SiO2 content magmas have higher viscosity than lower SiO2
content magmas
Lower Temperature magmas have higher viscosity than higher
temperature magmas.
Mostly H2O with some CO2
Minor amounts of Sulfur, Cl , and F
Rhyolitic or granitic magmas usually have higher gas contents than
basaltic or gabbroic magmas.
Temperature of Magmas
Basaltic or gabbroic - 1000-1200oC
Andesitic or dioritic - 800-1000oC
Rhyolitic or granitic - 650-800oC.
Viscosity of Magmas - Viscosity is the resistance to flow (opposite
of fluidity) Depends on composition, temperature, gas content.
Higher SiO2 content magmas have higher viscosity than lower SiO2
content magmas
Lower Temperature magmas have higher viscosity than higher
temperature magmas.
When magmas reach the surface of the Earth they erupt from a vent.
They may erupt explosively or non explosively.
Non explosive eruptions are favored by low gas content and low
viscosity magmas (basaltic to andesitic magmas).
Usually begin with fire fountains due to release of dissolved gases
Produce lava flows on surface
Produce Pillow lavas if erupted beneath water
Explosive eruptions are favored by high gas content and high
viscosity (andesitic to rhyolitic magmas).
Expansion of gas bubbles is resisted by high viscosity of magma -
results in building of pressure
High pressure in gas bubbles causes the bubbles to burst when
reaching the low pressure at the Earth's surface.
Bursting of bubbles fragments the magma into pyroclasts and tephra
(ash).
Cloud of gas and tephra rises above volcano to produce an eruption
column that can rise up to 45 km into the atmosphere.
If eruption column collapses a pyroclastic flow may occur, wherein
gas and tephra rush down the flanks of the volcano at high speed.
This is the most dangerous type of volcanic eruption. The deposits
that are produced arecalled ignimbrites.
Lateral blasts and debris avalanches occur when gas is released suddenly
by a large landslide or debris avalanche taking out part of the volcano
Origin of Magma
In order for magmas to form, some part of the earth must get hot enough to
melt the rocks present. Under normal conditions, the geothermal gradient
is not high enough to melt rocks, and thus with the exception of the outer
core, most of the Earth is solid. Thus, magmas form only under
special circumstances. To understand this we must first look at how
rocks and mineral melt.
As pressure increases in the Earth, the melting temperature changes as
well. For pure minerals, there are two general cases.
For a pure dry (no H2O or CO2 present) mineral, the melting temperate
increases with increasing pressure.
For a mineral with H2O or CO2 present, the melting temperature first
decreases with increasing pressure
Since rocks mixtures of minerals, they behave somewhat differently.
Unlike minerals, rocks do not melt at a single temperature, but instead
melt over a range of temperatures. Thus it is possible to have
partial melts, from which the liquid portion might be extracted to form
magma. The two general cases are:
Melting of dry rocks is similar to melting of dry minerals, melting
temperatures increase with increasing pressure, except there is a range of
temperature over which there exists a partial melt. The degree of
partial melting can range from 0 to 100%
Melting of rocks containing water or carbon dioxide is similar to melting
of wet minerals, melting temperatures initially decrease with increasing
pressure, except there is a range of temperature over which there exists a
partial melt.
Origin of Basaltic Magma
Much evidence suggests that Basaltic
magmas
result from dry partial melting of mantle.
Basalts make up most of oceanic crust and only mantle underlies
crust.
Basalts contain minerals like olivine, pyroxene and plagioclase,
none of which contain water.
Basalts erupt non-explosively, indicating a low gas content and
therefore low water content.
The Mantle is made of garnet peridotite
(a rock made up of olivine, pyroxene, and garnet) -- evidence comes from
pieces brought up by erupting volcanoes. In the laboratory we can
determine the melting behavior of garnet peridotite.
Under normal conditions the temperature in the Earth, shown by the
geothermal gradient, is lower than the beginning of melting of the
mantle. Thus in order for the mantle to melt there has to be a
mechanism to raise the geothermal gradient. Once such mechanism is
convection, wherein hot mantle material rises to lower pressure or depth,
carrying its heat with it. If the raised geothermal gradient becomes
higher than the initial melting temperature at any pressure, then a
partial melt will form. Liquid from this partial melt can be
separated from the remaining crystals because, in general, liquids have a
lower density than solids. Basaltic or gabbroic magmas appear to
originate in this way.
Most Granitic or Rhyolitic magma appears to result from wet melting of
continental crust. The evidence for this is:
Most granites and rhyolites are found in areas of continental crust.
When granitic magma erupts from volcanoes it does so very explosively,
indicating high gas content.
Solidified granite or rhyolite contains quartz, feldspar, hornblende,
biotite, and muscovite. The latter minerals contain water, indicating high
water content
Still, the temperature in continental crust is usually not high enough to
cause melting, and thus another heat source is necessary. In most
cases it appears that this heat source is basaltic magma. The
basaltic magma is generated in the mantle, then rises into the continental
crust. But, because basaltic magma has a high density it may stop in
the crust and crystallize, releasing heat into the surrounding crust. This
raises the geothermal gradient and may cause wet partial melting of the
crust to produce rhyolitic magmas.
Origin of Andesitic Magma
Average composition of continental crust is andesitic, but if andesite
magma is produced by melting of continental crust then it requires
complete melting of crust. Temperatures in crust unlikely to get high
enough. Andesitic magmas erupt in areas above subduction zones - suggests
relation between production of andesite and subduction. One theory
involves wet partial melting of subducted oceanic crust. But, newer
theories suggest wet partial melting of mantle.
Magmatic Differentiation
When magma solidifies to form a rock it does so over a range of
temperature. Each mineral begins to crystallize at a different
temperature, and if these minerals are somehow removed from the liquid,
the liquid composition will change. Depending on how many minerals are
lost in this fashion, a wide range of compositions can be made. The
processes is called magmatic differentiation by crystal fractionation.
Crystals can be removed by a variety of processes. If the crystals are
more dense than the liquid, they may sink. If they are less dense than the
liquid they will float. If liquid is squeezed out by pressure, then
crystals will be left behind. Removal of crystals can thus change the
composition of the liquid portion of the magma. Let me illustrate this
using a very simple case. Imagine a liquid containing 5 molecules of MgO
and 5 molecules of SiO2. Initially the composition of this magma is
expressed as 50% SiO2 and 50% MgO. i.e
Now let's imagine I remove 1 MgO molecule by putting it into a crystal and
removing the crystal from the magma. Now what are the percentages of each
molecule in the liquid?
If we continue the process one more time by removing one more MgO molecule
Thus, composition of liquid can be changed.
Bowen's Reaction Series
Bowen found by experiment that the order in which minerals crystallize
from a basaltic magma depends on temperature. As a basaltic magma is
cooled Olivine and Ca-rich plagioclase crystallize first. Upon
further cooling, Olivine reacts with the liquid to produce pyroxene and
Ca-rich plagioclase react with the liquid to produce less Ca-rich
plagioclase. But, if the olivine and Ca-rich plagioclase are removed
from the liquid by crystal fractionation, then the remaining liquid will
be more SiO2 rich. If the process continues, an original basaltic
magma can change to first and andesite magma then a rhyolite magma with
falling temperature
Basalts, Andesites, Dacites and Rhyolites are all types of volcanic rock
distinguished on the basis of their mineral assemblage. Depending on
conditions present during eruption and cooling, any of these rock types
may form one of the following types of volcanic rocks.
Obsidian - dark colored volcanic glass showing concoidal fracture.
Usually rhyolitic or dacitic.
Pumice - light colored and light weight rock consisting of mostly
holes (vesicles) that were once occupied by gas, Usually rhyolitic,
dacitic or andesitic.
Vesicular rock - rock filled with holes (Swiss cheese) or vesicles
that were once occupied by gas. Usually basaltic and andesitic.
Amygdaloidal basalt. If vesicles in a vesicular basalt are later
filled by precipitation of calcite or quartz, the fillings are termed
amygdules and the basalt is termed an amygdaloidal basalt.
Pyroclasts and Tephra Pyroclasts = hot, broken fragments. Result
from explosively ripping apart of magma. Loose assemblages of
pyroclasts called tephra. Depending on size, tephra can be classified
as bombs. lapilli, or ash.
Rock formed by accumulation and cementation of tephra called a
pyroclastic rock or tuff. Welding, compaction and deposition of other
grains cause tephra (loose material) to be converted in pyroclastic
rock.
Volcanoes
Shield volcano - volcanoes that erupt low viscosity magma (usually
basaltic) that flows long distances from the vent.
Pyroclastic cone or cinder cone - a volcano built mainly of tephra fall
deposits located immediately around the vent.
Stratovolcano (composite volcano) - a volcano built of interbedded lava
flows and pyroclastic material.
Crater - a depression caused by explosive ejection of magma or gas.
Caldera - a depression caused by collapse of a volcano into the cavity
once occupied by magma
Lava Dome - a steep sided volcanic structure resulting from the eruption
of high viscosity, low gas content magma
Thermal Springs and Geysers - hot water resulting from heating by magma at
depth in the Earth. Springs flow, geysers erupt.
Fissure Eruptions - An eruption that occurs along a narrow crack or
fissure in the Earth's surface.
Pillow Lava - Lavas formed by eruption beneath the surface of the ocean or
a lake.