source of diamonds
Source of Diamonds
Experiments and the high density of diamonds
tell us that they crystallize at very high pressures. In nature this
means
that diamonds are created by geologic processes at great depth within
Earth,
generally more than 150 kilometers down, in a region beneath the crust
known as the mantle. Other processes, bring diamonds to where people
can
find them.
This diagram shows the interior structure of Earth. The three concentric layers -- the core, mantle, and crust -- formed within a few hundred million years of Earth's coalescence 4.5billion years ago. The core is primarily an iron-nickel alloy and makes up a large fraction of the mass of Earth. The vast mantle is sandwiched between the core and the thin crust and is composed predominantly of magnesium and iron silicate minerals. Our planet's crust is a thin, rocky skin.
Diamonds can form in most of Earth's
interior but not near its surface, where graphite is the stable form of
carbon. Indeed, diamonds only survive at Earth's surface because great
heat is required to break down the diamond structure.

The upper mantle is slightly plastic,
which allows it to circulate slowly in a creeping, convective flow that
helps drive the surface motion of Earth known as "plate tectonics." The
cross section shown here provides a closer look at Earth's crust and
underlying
mantle. The crust can be divided into ocean basins, underlain by a thin
layer of dense, basaltic rock, and continents, formed of a much thicker
but less-dense layer of granitic rocks. Just below the crust is the
portion
of the mantle called the lithosphere, which is rigid and acts like
rock.
Below this is the asthenosphere, a more plastic, flowing region that
enables
the overlying crustal plates to move in what is known as plate
tectonics.

The plot of pressure and temperature
shows the conditions at which either diamond or graphite exist. The
general
conditions present in the Earth are described by curved lines called
geotherms.
Note that there are two geotherms: Because the continental crust is old
and thick, conditions are somewhat colder in and beneath it than
beneath
the much younger ocean basins. Diamonds can form at depths as shallow
as
150 kilometers beneath the continental crust, while beneath oceans they
need depths of at least 200 kilometers, as shown by the diamond
boundary
on the cross-section.
Diamond is amazingly dense. At 3.51
grams per cubic centimeter, it is vastly more dense than graphite --
the
more common form of the light element carbon -- at 2.20 grams per cubic
centimeter. This comparison offers an important clue to diamond's
origin:
The fact that diamond is "squeezed" much denser than graphite, which
forms
near Earth's surface, implies formation at high pressure. As shown on
the
graph, this concept was corroborated by experimental synthesis of
diamond
at high pressure and temperature.

This simplified diagram shows the conditions of pressure and temperature where diamond and graphite will be the stable forms of carbon. The points show the conditions at which diamonds were first grown by the companies ASEA and General Electric in the early 1950s. Temperatures are in Kelvin; subtract 273 to convert to degrees Celsius. This magnitude of high pressure is difficult to comprehend. For example, the pressure of 55,000 atmospheres necessary to make a diamond at 1400 degreesC (orange hot) would require:
The Eiffel Tower (7000 metric tons) resting on a 5 inch plate;
10 Anighito meteorites (10 X 20 metric
tons) resting on a 5 cent piece.